TY - JOUR AU - Mikhail Mamaev AU - Joseph Thywissen AU - Ana Maria Rey AB - We introduce protocols for designing and manipulating qubits with ultracold alkali atoms in 3D optical lattices. These qubits are formed from two-atom spin superposition states that create a decoherence-free subspace immune to stray magnetic fields, dramatically improving coherence times while still enjoying the single-site addressability and Feshbach resonance control of state-of-the-art alkali atom systems. Our protocol requires no continuous driving or spin-dependent potentials, and instead relies upon the population of a higher motional band to realize naturally tunable in-site exchange and cross-site superexchange interactions. As a proof-of-principle example of their utility for entanglement generation for quantum computation, we show the cross-site superexchange interactions can be used to engineer 1D cluster states. Explicit protocols for experimental preparation and manipulation of the qubits are also discussed, as well as methods for measuring more complex quantities such as out-of-time-ordered correlation functions (OTOCs). BT - Advanced Quantum Technologies DA - 2020-04 DO - 10.1002/qute.201900132 N2 - We introduce protocols for designing and manipulating qubits with ultracold alkali atoms in 3D optical lattices. These qubits are formed from two-atom spin superposition states that create a decoherence-free subspace immune to stray magnetic fields, dramatically improving coherence times while still enjoying the single-site addressability and Feshbach resonance control of state-of-the-art alkali atom systems. Our protocol requires no continuous driving or spin-dependent potentials, and instead relies upon the population of a higher motional band to realize naturally tunable in-site exchange and cross-site superexchange interactions. As a proof-of-principle example of their utility for entanglement generation for quantum computation, we show the cross-site superexchange interactions can be used to engineer 1D cluster states. Explicit protocols for experimental preparation and manipulation of the qubits are also discussed, as well as methods for measuring more complex quantities such as out-of-time-ordered correlation functions (OTOCs). PY - 2020 SE - 1900132 EP - 1900132 T2 - Advanced Quantum Technologies TI - Quantum computation toolbox for decoherence-free qubits using multi-band alkali atoms UR - https://onlinelibrary.wiley.com/doi/full/10.1002/qute.201900132 VL - 3 ER -