TY - JOUR
AU - K. Catani
AU - J. Greenberg
AU - B. Saarel
AU - Heather Lewandowski
AB - Ion–neutral chemical reactions are important in several areas of chemistry, including in some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of CCl+ with C2H2 are measured, and the main products include C3H2+ and C3H+, both relevant in extraterrestrial environments. Accurate branching ratios are obtained, which favor the formation of C3H2+ over C3H+ by a factor of four. The measured rate constants are on the order of Langevin, and complementary electronic structure calculations are used to aid in the interpretation of experimental results.
BT - The Journal of Chemical Physics
DA - 2020-06
DO - 10.1063/5.0008656
IS - 23
N2 - Ion–neutral chemical reactions are important in several areas of chemistry, including in some regions of the interstellar medium, planetary atmospheres, and comets. Reactions of CCl+ with C2H2 are measured, and the main products include C3H2+ and C3H+, both relevant in extraterrestrial environments. Accurate branching ratios are obtained, which favor the formation of C3H2+ over C3H+ by a factor of four. The measured rate constants are on the order of Langevin, and complementary electronic structure calculations are used to aid in the interpretation of experimental results.
PB - AIP Publishing
PY - 2020
SE - 234310
EP - 234310
T2 - The Journal of Chemical Physics
TI - Reactions of translationally cold trapped CCl+ with acetylene (C2H2)
VL - 152
SN - 0021-9606, 1089-7690
ER -